121676-01-5

Basic information

• Product Name: 3-Methylbicyclo<2.2.1>hepta-2,5-dien-2-carboxaziridid
• CAS NO: 121676-01-5
• Molecular Weight: 175.23
• Mol File: 121676-01-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Methylbicyclo<2.2.1>hepta-2,5-dien-2-carboxaziridid(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methylbicyclo<2.2.1>hepta-2,5-dien-2-carboxaziridid(121676-01-5)
• EPA Substance Registry System: 3-Methylbicyclo<2.2.1>hepta-2,5-dien-2-carboxaziridid(121676-01-5)

Safety Data

• Hazardous Substances Data: 121676-01-5(Hazardous Substances Data)

Upstream product

• 151-56-4 ethyleneimine 
• 121675-98-7 3-Methylbicyclo<2.2.1>hepta-2,5-dien-2-carbonylchlorid 

Downstream Products

• 121676-06-0 5-Methyltetracyclo<3.2.0.0^2,7.0^4,6>heptan-1-carboxaziridid 

Relevant articles and documents

Experiments towards the Generation of 1,5- and 2,3-Didehydroquadricyclanes

Metalation of the (hydroxymethyl)quadricyclanes 7a - c with n-butyllithium in ether is determined mostly by the chelating effect of the CH2O-Li group and only to a lesser extent by the magnitude of the 13C-1H coupling constant of the position to be lithiated in the corresponding quadricyclane derivative.Similar results were obtained for 3-quadricyclanol (20a).Treatment of the bromide 26a, prepared by lithiation of 7b, with strong bases apparently generates the 1,2-didehydroquadricyclane 34.and not the 1,5-didehydroquadricyclane 35.Attempts to convert the dihalide 9 into the 2,3-didehydroquadricyclane 4 were unsuccessful.