121680-92-0Relevant articles and documents
A Mild Method for the Conversion of 1,3-Glycols into Unsaturated Alcohols
Ackland, Mark J.,Gordon, John F.,Hanson, James R.,Yeoh, Boon Leng,Ratcliffe, Arnold H.
, p. 2013 - 2018 (2007/10/02)
Some transformations of 1,3-glycols utilizing dimethylformamide dimethyl acetal have been examined with the diterpenoids aphidicolin and foliol and some steroids as substrates.Axial alcohols with a suitably disposed trans hydrogen atom undergo an elimination reaction to give the formate of an unsaturated alcohol via the quaternary salt of the cyclic formamido acetal.
