1216833-92-9Relevant academic research and scientific papers
DHTP Ligands for the highly ortho-selective, palladium-catalyzed cross-coupling of dihaloarenes with grignard reagents: A conformational approach for catalyst improvement
Ishikawa, Shunpei,Manabe, Kei
supporting information; experimental part, p. 772 - 775 (2010/04/24)
(Chemical Equation Presentation) Palladium catalysts bearing dihydroxyter-phenylphosphine ligands (such as 1) are reported for the ortho-selective cross-coupling of Grignard reagents and dihaloarenes. The second hydroxy group onto the terphenylphosphine ligand dramatically improved the catalytic efficiency and expanded the scope of the reaction.
