12170-15-9

Upstream product

• 179864-66-5 tricarbonyl[(((1,2,3,4,5,6-η)-2-(1-oxopropyl)phenyl)-C,O)tetracarbonylmanganese]chromium 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 12155-45-2 (trans-stilbene)tricarbonylchromium 
• 84415-04-3 Cr(CO)3C₆H₅CH₂CH₂C(C₆H₅)NC₆H₅ 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 1581701-39-4 C-(η⁶-phenylchromium tricarbonyl)-N-methylnitrone 
• 874889-70-0 [Cr(CO)3(C₆H₅CHPC₆H₂(C(CH₃)3)3)] 
• 804562-50-3 Cr(CO)3(C₆H₅CHN(O)CH₂C₆H₅) 
• 245118-66-5 (η(6)-C6H5CH(OCOCH3)-C*CPh)Cr(CO)3 
• 155890-73-6 (CO)3Cr{(C₆H₅)C₃H₃O₂(C₆H₅)2} 

Relevant academic research and scientific papers

Chemistry of unsaturated arenetricarbonylchromium compounds 1. Reaction of (η6-arene)tricarbonylchromium complexes of nitrones with methyl phenylpropiolate

The reactions of nitrones of the composition (CO)3CrC6H5CH=N+(O-)R (R = Me, Ph, or But) with substituted acetylene were studied. The reactions proceed with high regioselectivity and give 4-

Synthesis and reactions of [(((η6)-2-acylaryl)-C,O) tetracarbonylmanganese]-tricarbonylchromium complexes: Enhancement of diastereoselection during cyclopentaannulation

Cyclomanganation reactions of [(η6)-acylaryl]tricarbonylchromium complexes have been investigated. Three novel heterobimetallic complexes have been synthesised in moderate to good yield, with one being characterised by X-ray crystallography. Several modes of activating these bimetallic complexes towards coupling reactions with substituted alkenes and alkynes were investigated, including oxidative decarbonylation at room temperature, and thermal promotion. The stereochemistry of one of the cyclopentaannulated adducts has been established by X-ray crystallography. Thermal displacement of one of the CO ligands of the bimetallic complex 27 in the presence of PPh3 afforded a single adduct, the structure of which was established by X-ray crystallography. The chemistry of this novel bimetallic system was investigated.