1217298-38-8

Basic information

• Product Name: C₈H₇ClO₃*C₁₀H₁₅OP
• CAS NO: 1217298-38-8
• Molecular Weight: 368.797
• Mol File: 1217298-38-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₈H₇ClO₃*C₁₀H₁₅OP(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₇ClO₃*C₁₀H₁₅OP(1217298-38-8)
• EPA Substance Registry System: C₈H₇ClO₃*C₁₀H₁₅OP(1217298-38-8)

Safety Data

• Hazardous Substances Data: 1217298-38-8(Hazardous Substances Data)

Upstream product

• 7138-34-3 p-chloromandelic acid 
• 82945-11-7 (R_p)-t-butyl(phenyl)phosphine oxide 

Relevant articles and documents

Enantiopure tert-butyl(phenyl)phosphine oxide. Chirality-recognition ability and mechanism

When enantiopure tert-butyl(phenyl)phosphine oxide 1 was used as a resolving agent, it showed an acceptable to good chirality-recognition ability for several kinds of racemic carboxylic acids 2. A study on a chirality-recognition mechanism based on X-ray crystallographic analyses of the diastereomeric complexes of 2 with 1 revealed that the complex crystals consisted of helical columns and that 1 was not responsible for the formation of the helical column and occupied a void between the columns; although 1 interacted with 2 via a hydrogen bond to primarily form a pair with 2, the complex crystals were mainly stabilized by the accumulation of weak interactions, such as CH/π, π/π and CH...O interactions, between 1/1, 1/2 and 2/2.