1217367-30-0Relevant academic research and scientific papers
Green synthesis of vicinal dithioethers and alkenyl thioethers from the reaction of alkynes and thiols in water
Jin, Zhuang,Xu, Bo,Hammond, Gerald B.
supporting information; experimental part, p. 168 - 173 (2010/03/24)
The reaction of a wide range of alkynes with thiols to give vicinal dithioethers in water, under mild conditions, is reported. In addition, non-terminal propargyl alcohols react with aryl thiols in water to produce a highly regio-and stereoselective monohydrothiolation product, (E)-alkenyl thioether. Reaction mechanism and computational studies on the selectivity of the product are presented.
