121846-03-5

Basic information

• Product Name: 1-(7,11-Anhydro-8-O-benzoyl-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil
• Synonyms: 1-(7,11-Anhydro-8-O-benzoyl-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil
• CAS NO: 121846-03-5
• Molecular Weight: 680.709
• Mol File: 121846-03-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(7,11-Anhydro-8-O-benzoyl-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(7,11-Anhydro-8-O-benzoyl-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil(121846-03-5)
• EPA Substance Registry System: 1-(7,11-Anhydro-8-O-benzoyl-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil(121846-03-5)

Safety Data

• Hazardous Substances Data: 121846-03-5(Hazardous Substances Data)

Upstream product

• 121846-02-4 Benzoic acid 2-((R)-2-{(3aR,4R,6R,6aR)-6-[3-(4-methoxy-benzyl)-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl]-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl}-2-methoxymethoxy-ethyl)-4-oxo-3,4-dihydro-2H-pyran-3-yl ester 
• 362-43-6 2',3'-O-isopropylideneuridine 
• 32464-93-0 1-(2,3-O-Isopropylidene-β-D-ribofuranosyl)-3-(4-methoxybenzyl)uracil 
• 121846-01-3 1-(6-Deoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-β-D-allo-heptadialdo-1,4-furanosyl)-3-(4-methoxybenzyl)uracil 
• 121846-00-2 1-(6,7,8-Trideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-β-D-allo-oct-7-enofuranosyl)-3-(4-methoxybenzyl)uracil 
• 121845-99-6 1-(6,7,8-Trideoxy-2,3-O-isopropylidene-β-D-allo-oct-7-enofuranosyl)-3-(4-methoxybenzyl)uracil 
• 121845-98-5 (3aR,4S,6R,6aS)-6-(3-(4-methoxybenzyl)-3,4-dihydro-2,4-dioxopyrimidin-1(2H)-yl)-tetrahydro-2,2-dimethylfuro[3,4-d][1,3]dioxole-4-carbaldehyde 
• 15922-23-3 1-(5-O-Acetyl-2,3-O-isopropylidene-β-D-ribofuranosyl)uracil 

Downstream Products

• 121865-31-4 3-(4-Methoxybenzyl)-1--2,6-dideoxy-3,4:9,10-di-O-isopropylidene-7-O-(methoxymethyl)-L-allo-β-D-galacto-undecodialdo-1,5-pyranoside-11,8-furanosyl>uracil 
• 121846-06-8 3-(4-Methoxybenzyl)-1-<(11R)-1,2,6-trideoxy-3,4:9,10-di-O-isopropylidene-7-O-(methoxymethyl)-L-allo-α-D-galacto-undecodialdo-1,5-pyrano<2,1-e><2-(benzyloxy)-4-(benzyloxycarbonyl)dihydro-Δ²-1,3,4-oxadiazinyl>-11,8-furanosyl>uracil 
• 121846-09-1 3-(4-Methoxybenzyl)-1--2,6-dideoxy-3,4:9,10-di-O-isopropylidene-7-O-(methoxymethyl)-L-allo-β-D-galacto-undecodialdo-1,5-pyranoside-11,8-furanosyl>uracil 
• 121846-07-9 3-(4-Methoxymethyl)-1-uracil 
• 121846-05-7 1-(7,11-Anhydro-6,10-dideoxy-2,3:8,9-di-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil 
• 121846-04-6 1-(7,11-Anhydro-6,10-dideoxy-2,3-O-isopropylidene-5-O-(methoxymethyl)-D-arabino-β-D-allo-undec-10-enofuranosyl)-3-(4-methoxybenzyl)uracil 

Relevant articles and documents

Fully synthetic stereoselective routes to the differentially protected subunits of the tunicamycins

Total synthesis of the two subunits corresponding to tunicamycins have been achieved. One of the key steps involves a cyclocondensation reaction of 7-carbon aldehydo nucleoside with activated diene 8 under catalysis with stannic chloride (see 7 + 8→9a,b). Stereospecific Fitzsimmons cycloadditions of dibenzyl azodicarboxylate to galactal 12 and glucal 22 simplified construction of the amino pyranose systems.