1218787-83-7

Basic information

• Product Name: 1-(2-bromobenzenesulfonyl)-2,5-dihydro-3-methyl-1H-pyrrole
• Synonyms: 1-(2-bromobenzenesulfonyl)-2,5-dihydro-3-methyl-1H-pyrrole
• CAS NO: 1218787-83-7
• Molecular Weight: 302.192
• Mol File: 1218787-83-7.mol

Chemical Properties

• CAS DataBase Reference: 1-(2-bromobenzenesulfonyl)-2,5-dihydro-3-methyl-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-bromobenzenesulfonyl)-2,5-dihydro-3-methyl-1H-pyrrole(1218787-83-7)
• EPA Substance Registry System: 1-(2-bromobenzenesulfonyl)-2,5-dihydro-3-methyl-1H-pyrrole(1218787-83-7)

Safety Data

• Hazardous Substances Data: 1218787-83-7(Hazardous Substances Data)

Upstream product

• 2905-25-1 o-bromobenzenesulfonyl chloride 
• 1218787-92-8 N-allyl-N-2-methylallyl-2-bromobenzenesulfonamide 

Downstream Products

• 1218787-84-8 1-methyl-8-thia-9-azatricyclo[7.2.1.02,7]dodeca-2⁽⁷⁾,3,5,10-tetraene-8,8-dioxide 
• 1421639-28-2 C₁₁H₁₀BrNO₂S 

Relevant articles and documents

Selective generation of quaternary all-carbon-centres through Heck-cyclisations: Synthesis of mesembrane

Described is an observation that the intramolecular Heck reaction of a trisubstituted alkene proceeds with high regioselectivity and leads to the preferential formation of a quaternary all-carbon-centre. This observation was subsequently applied in a short synthesis of (±)-mesembrane. The Royal Society of Chemistry 2010.

Regioselectivity in the intramolecular heck reaction of a series of cyclic sulfonamides: An experimental and computational study

Regioselectivity in the intramolecular Heck reaction of a series of N-sulfonyl-2,5-dihydro-3-substituted pyrroles was studied. These substrates are unbiased in terms of the formed ring size of the new heterocycle. Results indicate that high levels of regi