1218923-18-2Relevant academic research and scientific papers
A three-coordinate copper(II) amide from reductive cleavage of a nitrosamine
Melzer, Marie M.,Mossin, Susanne,Dai, Xuliang,Bartell, Ashley M.,Kapoor, Pooja,Meyer, Karsten,Warren, Timothy H.
, p. 904 - 907 (2010/06/11)
A NO-velty: A copper(1) β-diketiminate activates the nitrosamine Ph2NNO to give a rare, three-coordinate copper(II) amide, [(Me 2NN)Cu-NPh2]. Reaction of this amide with NOgas returns Ph2NNO as well as a mixed-valence species with NOfunctionalized β-diketiminate ligands (see scheme; Cu light blue, N dark blue, O red). Thus, both the cleavage and formation of R2N-NO bonds may take place at a common copper center. (Figure Presented)
