1219090-76-2Relevant academic research and scientific papers
Novel Glycosidation of - D -Altropyranosides
Nakayama, Takahiro,Nishiyama, Kazusa,Natsugari, Hideaki,Takahashi, Hideyo
, p. 43 - 48 (2010)
A new glycosidation of α-d-altropyranosides, in which the 2-hydroxy group is not protected, was developed. The reaction proceeds via a 1,2 -β oxirane, which is formed in situ without extra steps for exchanging the 1-methoxy group to a more reactive leaving group. The glycoside bond of α-d-altropyranoside was shown to be weaker compared with those of α-d-glucopyranoside and α-d-mannopyranoside.
