1219155-98-2Relevant academic research and scientific papers
A divergent mechanistic course of Pd(0)-catalyzed aza-claisen rearrangement and aza-rautenstrauch-type cyclization of N -allyl ynamides
Dekorver, Kyle A.,Hsung, Richard P.,Lohse, Andrew G.,Zhang, Yu
supporting information; experimental part, p. 1840 - 1843 (2010/10/03)
A fascinating mechanistic study of ynamido-palladium-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can be accompanied by an unusual thermal N-to-C 1,3-Ts shift in the formation of tertiary nitriles and a novel cyclopentenimine formation via a palladium-catalyzed aza-Rautenstrauch-type cyclization pathway.
