121916-59-4

Upstream product

• 121811-39-0 DL-(1α,2β,3β,4α,6β)-1-O-acetyl-2-O,3-N-carbonyl-6-iodo-4-O-methyl-3-(methylamino)-1,2,4-cyclohexanetriol 
• 121811-44-7 DL-(1α,2β,3β,4α,6β)-6-bromo-2-O,3-N-carbonyl-4-O-methyl-3-(methylamino)-1,2,4-cyclohexanetriol 
• 87902-30-5 DL-(1α,2α,3β,4β,5α)-1,2-anhydro-3-O,4-N-carbonyl-5-O-methyl-4-(methylamino)-1,2,3,5-cyclohexanetetrol 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 121811-46-9 DL-(1α,2β,3β,4α,6β)-6-bromo-2-O,3-N-carbonyl-4-O-methyl-3-(methylamino)-1-O-(phenoxycarbonyl)-1,2,4-cyclohexanetriol 

Relevant academic research and scientific papers

Aminoglycoside Antibiotics - Enantiomerically Pure Sporamine Building Blocks

Starting from the 1,2:4,5-dianhydro-epi-deoxyinositol 2a (available ultimately from benzene) an expedient total synthesis of rac-sporamine (rac-3) has been developed.Key steps are two regiospecific and quantitative epoxide openings, effected intramolecula