1219610-10-2Relevant academic research and scientific papers
PPh3-catalyzed reactions of alkyl propiolates with N-tosylimines: A facile synthesis of alkyl 2-[aryl(tosylimino)methyl]acrylate and an insight into the reaction mechanism
Liu, Huimin,Zhang, Qiongmei,Wang, Limin,Tong, Xiaofeng
supporting information; experimental part, p. 1968 - 1972 (2010/06/19)
A new PPh3-catalyzed synthesis of alkyl 2-[aryl(tosylimino) methyl]acrylates from propiolate and N-tosylimine has been developed. Deuterium-labelling experiments show that the reaction mechanism involves several hydrogen-transfer processes, whi
