121963-57-3Relevant academic research and scientific papers
Csp3-Csp2 palladium-catalyzed cross-coupling reaction of trialkylbismuth reagents with aryl, heteroaryl, and vinyl halides and triflates
Gagnon, Alexandre,Albert, Vincent,Duplessis, Martin
experimental part, p. 2936 - 2940 (2011/02/28)
The palladium-catalyzed cross-coupling reaction of trialkylbismuth reagents with aryl and heteroaryl halides and triflates is reported. Moderate to good yields were obtained for the transfer of primary alkyl groups. The reaction tolerates numerous functional groups on the electrophilic and nucleophilic partners. The cross-coupling of -bromostyrene with tris(1,3-dioxan-2-ylethyl) bismuth is also reported. Georg Thieme Verlag Stuttgart - New York.
Synthesis of Alkyl-Substituted N-Protected Indoles via Acylation and Reductive Deoxygenation
Ketcha, Daniel M.,Lieurance, Brett A.,Homan, Dominic F. J.,Gribble, Gordin W.
, p. 4350 - 4356 (2007/10/02)
The synthesis of 2-, 3-, and 5-alkyl-1-(phenylsulfonyl)indoles involving Friedel-Crafts acylation followed by reductive deoxygenation is described.The application of this acylation-deoxygenation sequence to 3-acyl-1-(phenylsulfonyl)indoles bearing potenti
