1219798-55-6

Basic information

• Product Name: 4-Methoxyaniline--d4
• Synonyms: 4-Methoxyaniline--d4
• CAS NO: 1219798-55-6
• Molecular Formula: C₇H₉NO
• Molecular Weight: 127.177107112
• Mol File: 1219798-55-6.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• Storage Temp.: Refrigerator, under inert atmosphere
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 4-Methoxyaniline--d4(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methoxyaniline--d4(1219798-55-6)
• EPA Substance Registry System: 4-Methoxyaniline--d4(1219798-55-6)

Safety Data

• Hazardous Substances Data: 1219798-55-6(Hazardous Substances Data)

Relevant articles and documents

EPR and ENDOR spectroscopic study of the reactions of aromatic azides with gallium trichloride

The reactions of gallium trichloride with phenyl and deuterio-phenyl azides, as well as with 4-methoxyphenyl azide and deuterium isotopomers, were examined by product analysis, CW EPR spectroscopy and pulsed ENDOR spectroscopy. The products included the corresponding anilines together with 4-aminodiphenylamine type dimers, and polyanilines. Complex CW EPR spectra of the radical cations of the dimers [ArNHC6H4NH 2]+ and trimers [ArNHC6H4NHC 6H4NH2]+ were obtained. These EPR spectra were analysed with the help of data from the deuterium-substituted analogues as well as the pulse Davies ENDOR spectra. DFT computations of the radical cations provided corroborating evidence and suggested the unpaired electrons were accommodated in extensive π-delocalised orbitals. A mechanism to account for the reductive conversion of aromatic azides to the corresponding anilines and thence to the dimers and trimers is proposed.