1219937-63-9Relevant academic research and scientific papers
A new access to the 6,8-dioxabicyclo[3.2.1]octane ring system using a three-component reaction: Enantioselective synthesis of (+)-iso- exo -brevicomin
Bouziane, Asmae,Régnier, Thomas,Carreaux, Fran?ois,Carboni, Bertrand,Bruneau, Christian,Renaud, Jean-Luc
experimental part, p. 207 - 210 (2010/04/02)
The combination of a catalytic hetero-Diels-Alder-allylboration sequence and a ruthenium-catalyzed isomerization of an allylic alcohol moiety as key steps open a new route for the asymmetric synthesis of 6,8-dioxabicyclo[3.2.1] octane subunits. The application of this strategy to the synthesis of (+)-iso-exo-brevicomin is also reported. Georg Thieme Verlag Stuttgart - New York.
