1219970-82-7Relevant articles and documents
Total synthesis of (+)-asperolidec by iridium-catalyzed enantioselective polyene cyclization
Jeker, Oliver F.,Kravina, Alberto G.,Carreira, Erick M.
, p. 12166 - 12169 (2013)
Domino rings: A general synthetic entry into labdane-type diterpenoids has been developed based on an iridium-catalyzed enantioselective polyene cyclization cascade. The potential of this process is demonstrated in the first total synthesis of the tetranorlabdane diterpene asperolideC (PMB=p-methoxybenzyl, TMS= trimethylsilyl). Copyright