1220103-59-2Relevant academic research and scientific papers
Synthesis of tetrathiafulvalene-containing zirconium(IV) pincers and metallocavitands for hosting fullerenes
Iden, Hassan,Morin, Jean-Fran?ois,Fontaine, Frédéric-Georges
, p. 235 - 242 (2014)
The synthesis and spectroscopic characterization of zirconium(IV) dicarboxylate 1 and metallocavitand 2 are described. Encapsulation studies of fullerenes C60 and C70 were performed using UV-Vis spectroscopy in chlorobenzene, toluene, benzene, carbon disulfide and in a mixture of toluene/dichloromethane. UV-Vis titrations have shown that the binding abilities of the hosts toward fullerene C70 are considerably higher than those obtained for fullerene C60.
