1220112-16-2Relevant academic research and scientific papers
Synthesis and reactivity of dipropargylic disulfides: tandem rearrangements, cyclization, and oxidative dimerization
Braverman, Samuel,Cherkinsky, Marina,Meridor, David,Sprecher, Milon
experimental part, p. 1925 - 1930 (2010/04/24)
Synthesis and facile rearrangement and cyclization reaction of new dipropargylic disulfides are described. A possible mechanism for these transformations involving an initial double [2,3]-sigmatropic rearrangement to the elusive diallenyl disulfides via a thiosulfoxide intermediates is suggested.
