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2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole, also known as P^iPrCyc or DPhpg, is a chemical compound that belongs to the family of phosphine ligands. It is a versatile and efficient ligand, known for its ability to impart high enantioselectivity and catalytic activity in asymmetric synthesis. P^iPrCyc has a unique structure, containing a cyclododecyl and phenyl substituents on the phosphorus atom, which impart distinctive steric and electronic properties that make it an important tool in synthetic chemistry.

1220126-18-0

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1220126-18-0 Usage

Uses

Used in Organic Chemistry:
2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole is used as a chiral ligand for various metal-catalyzed reactions in organic chemistry. Its application is due to its ability to provide high enantioselectivity and catalytic activity, making it a valuable tool in asymmetric synthesis.
Used in Inorganic Chemistry:
In inorganic chemistry, 2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole is used as a chiral ligand for metal-catalyzed reactions. Its unique structure and properties contribute to its effectiveness in these reactions, enhancing the overall performance of the catalytic processes.
Used in Asymmetric Hydrogenation:
2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole is used as a ligand in asymmetric hydrogenation reactions. Its application is due to its ability to impart high enantioselectivity, which is crucial for the production of chiral compounds with specific stereochemistry.
Used in Hydroformylation:
In hydroformylation reactions, 2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole is used as a ligand to enhance the catalytic activity and selectivity of the process. Its unique steric and electronic properties contribute to the efficiency of the reaction, leading to the formation of desired aldehyde products with high selectivity.

Check Digit Verification of cas no

The CAS Registry Mumber 1220126-18-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,2,0,1,2 and 6 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1220126-18:
(9*1)+(8*2)+(7*2)+(6*0)+(5*1)+(4*2)+(3*6)+(2*1)+(1*8)=80
80 % 10 = 0
So 1220126-18-0 is a valid CAS Registry Number.

1220126-18-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name dicyclohexyl-(1-methyl-3-phenylindol-2-yl)phosphane

1.2 Other means of identification

Product number -
Other names 2-(Dicyclohexylphosphino)-1-methyl-3-phenyl-1H-indole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1220126-18-0 SDS

1220126-18-0Downstream Products

1220126-18-0Relevant academic research and scientific papers

Synthesis of 2-indolylphosphines by palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines

Kondoh, Azusa,Yorimitsu, Hideki,Oshima, Koichiro

supporting information; experimental part, p. 1476 - 1479 (2010/06/15)

(Figure Presented) Palladium-catalyzed annulation of 1-alkynylphosphine sulfides with 2-iodoanilines followed by desulfidation affords 3-substituted 2-indolylphosphines. This annulatlon/desulfidation sequential protocol offers a conceptually new approach

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