122070-07-9Relevant academic research and scientific papers
Structure and reactivity of lithium diisopropylamide in the presence of N,N,N′,N′-tetramethylethylenediamine
Bernstein, Max P.,Romesberg, Floyd E.,Fuller, David J.,Harrison, Aidan T.,Collum, David B.,Liu, Qi-Yong,Williard, Paul G.
, p. 5100 - 5110 (1992)
Lithium diisopropylamide (LDA) crystallizes from N,N,N′,N′-tetramethylethylenediamine (TMEDA)/hexane mixtures as an infinite array of dimers linked by bridging (nonchelating) TMEDA ligands. 6Li and 15N NMR spectroscopic studio, revea
Structure and Reactivity of Lithium Diisopropylamide (LDA). The Consequences of Aggregation and Solvation during the Metalation of an N,N-Dimethylhydrazone
Galiano-Roth, Angela S.,Collum, David B.
, p. 6772 - 6778 (1989)
(6)Li and (15)N NMR spectroscopic studies of (6)Li-labeled and (6)Li,(15)N-doubly-labeled lithium diisopropylamide (LDA) are consistent with a disolvated dimer.Revision of a reported monomer-dimer equilibrium is suggested.Rate studies on the lithiation of
