122080-23-3Relevant articles and documents
Asymmetric Diels-Alder Reactions. Part 2. A Model to Account for the Diastereofacial Reactivity of (E)-1-(2',3',4',6'-Tetra-O-acetyl-β-D-glucopyranosyloxy)-3-trimethylsiloxybuta-1,3-diene and its 2-Methyl Derivative. X-Ray Molecular Structure of (E)-1-(2'
Gupta, Ramesh C.,Larsen, David S.,Stoodley, Richard J.,Slawin, Alexandra M.Z.,Williams, David J
, p. 739 - 749 (2007/10/02)
The geometry of the title diene (1a) has been probed by X-ray crystallography and nuclear Overhauser difference (n.O.e.d.) spectroscopy.In the crystal state, the sugar adopts the expected chair conformation and the equatorially disposed anomeric substitue