1221147-80-3

Basic information

• Product Name: ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-3-trifluoromethanesulfonyl-β-D-glucopyranoside
• Synonyms: ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-3-trifluoromethanesulfonyl-β-D-glucopyranoside
• CAS NO: 1221147-80-3
• Molecular Weight: 573.568
• Mol File: 1221147-80-3.mol

Chemical Properties

• CAS DataBase Reference: ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-3-trifluoromethanesulfonyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-3-trifluoromethanesulfonyl-β-D-glucopyranoside(1221147-80-3)
• EPA Substance Registry System: ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-3-trifluoromethanesulfonyl-β-D-glucopyranoside(1221147-80-3)

Safety Data

• Hazardous Substances Data: 1221147-80-3(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 99409-33-3 ethyl 4,6-O-benzylidene-2-deoxy-2-N-phthalamido-1-thio-β-Dglucopyranoside 

Downstream Products

• 210472-33-6 ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-β-D-allopyranoside 

Relevant articles and documents

Bis(oxazolines) based on glycopyranosides - Steric, configurational and conformational influences on stereoselectivity

In previous studies we found that the asymmetric induction of bis(oxazolines) based on D-glucosamine strongly depended on the steric demand of the 3-O-substituents. To further probe the impact of the 3-position of the pyranose scaffold, we prepared 3-epimerised and 3-defunctionalised versions of these ligands as well as a 3-O-formyl derivative. Application of these new ligands in asymmetric cyclopropanation revealed strong steric and configurational effects of position 3 on asymmetric induction, further dramatic effects of the pyranose conformation were also observed.