1221277-70-8Relevant articles and documents
Synthesis of a photoswitchable azobenzene-functionalized tris(indazol-1-yl) borate ligand and its ruthenium(II) cyclopentadienide complex
Jacquot de Rouville, Henri-Pierre,Villenave, Damien,Rapenne, Gwéna?l
, p. 1885 - 1891 (2010)
In this paper, the design and synthesis of a new indazole bearing a photoisomerizable fragment at its 4-position are presented as well as the photoisomerization studies on both the indazole precursor and the final ruthenium model complex. It was obtained after five steps, the last one being the cleavage of the indazole protecting group. Reaction of 1 equiv of this functionalized indazole with 2 equiv of plain indazole and dibromophenylborane gave access to a mixture of four tripodal ligands of the tris(indazolyl)borate family. In a last step, complexation of this mixture with [RuCp(CH3CN)3]PF6 yielded the corresponding ruthenium complexes from which the target ruthenium complex coordinated to a dissymmetric azobenzene-functionalized tripodal ligand was successfully isolated. Photoisomerization occured reversibly upon irradiation with UV light at 365 nm.
