122135-16-4

Basic information

• Product Name: 4-(m-nitrophenyl)-5-cyano-3-methyl-p-tolylpyrazole
• CAS NO: 122135-16-4
• Molecular Weight: 318.335
• Mol File: 122135-16-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(m-nitrophenyl)-5-cyano-3-methyl-p-tolylpyrazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(m-nitrophenyl)-5-cyano-3-methyl-p-tolylpyrazole(122135-16-4)
• EPA Substance Registry System: 4-(m-nitrophenyl)-5-cyano-3-methyl-p-tolylpyrazole(122135-16-4)

Safety Data

• Hazardous Substances Data: 122135-16-4(Hazardous Substances Data)

Upstream product

• 23813-31-2 (α-nitroethylidene)-p-tolylhydrazine 
• 2826-32-6 3-nitrobenzylidenemalononitrile 
• 122135-19-7 C₉H₁₀N₃O₂^(1-)*Na⁽¹⁺⁾ 

Relevant articles and documents

Thermal reaction of sodium salts of α-nitrohydrazones with arylidenemalonitriles and α,β-unsaturated ketones

A mixture of sodium salt of (α-nitroethylidene)-p-tolylhydrazine (1b) and arylidenemalonitriles (3a-g) when refluxed in acetonitriles gives 5-cyano-1,3-diaryl-3-methylpyrazoles (6a-g) reespectively.Similar reaction of 1 and benzyldieneacetophenones (4) yields 5-aroyl-1,4-diaryl-3-methyl-2-pyrazolines (7).Formation of 6 and 7 can be visualised as involving intermolecular cycloaddition of nitrilimines (2) generated in situ via thermal elimination of sodium nitrite from 1 to the dipolarophiles 3 and 4 respectively.