122166-32-9Relevant academic research and scientific papers
Nucleophilic Organosilicon Intermediates Turned Electrophilic:(Trimethylsilyl)metyl, Trimethylsilyloxy and also 2-Tetrahydropyranyloxy as Terminators of Cycloadditions of Allyl Cations. A Short Route to Dehydrozizaenes (6-Methylenetricyclo1,5>-undec-9,10-enes) and Related Tr...
Hoffman, H.M.R.,Eggert, Ulrike,Gibbels, Uwe,Giesel, Kunibert,Koch, Oskar,et al.
, p. 3899 - 3918 (2007/10/02)
A range of suitable precursors were synthesized in order to contrast and use Me3SiCH2-, Me3Sio- and THPO-groups as terminators in both inter- and intramolecular cycloadditions of allyl cations to cyclic 1,3-dienes.A variety of crowded bicyclic, and spirofused adducts with skeletons were obtained.The compounds are of interest, e.g., in perfumery.The work contributes to the development of carbocation-induced cyclization methodology.
