122183-78-2Relevant academic research and scientific papers
Structure and Conformation of α'-Diphenylphosphinoyl Enones: X-Ray Structure of E-(5SR,6SR)-3,6-Dimethyl-5-diphenylphosphinoyl-7-triphenylmethoxyhept-2-en-4-one
Doyle, Michael J.,Hall, David,Raithby, Paul R.,Skelton, Nicholas,Warren, Stuart
, p. 517 - 524 (2007/10/02)
A series of α'-diphenylphosphinoyl enones has been prepared and their s-cis or s-trans conformations correlated with 1H NMR and IR spectra and an X-ray crystal structure of the title compound.The effect of chelation to cerium(III) is correlated with the r
REVERSED STEREOCHEMICAL CONTROL IN THE REGIOSELECTIVE REDUCTION OF HINDERED DIPHENYLPHOSPHINOYL (Ph2PO-) KETONES AND ENONES
Elliott, Jason,Hall, David,Warren, Stuart
, p. 601 - 604 (2007/10/02)
Reduction of α'-diphenylphosphinoyl enones (6) and crowded α-diphenylphosphinoyl ketones (4) with sodium borohydride in the presence of cerium chloride gives the otherwise difficult to obtain erythro-alcohols (5) and (7).
