122186-40-7

Upstream product

• 60523-66-2 2-(2,3,4,6-tetra-О-acetyl-β-d-glucopyranosyloxy)benzyl bromide 
• 14581-83-0 helicin acetate 
• 90-02-8 salicylaldehyde 
• 5346-66-7 2-methylphenyl-(2,3,4,6-tetra-O-acetyl)-β-D-glucopyranoside 

Downstream Products

• 60523-66-2 2-(2,3,4,6-tetra-О-acetyl-β-d-glucopyranosyloxy)benzyl bromide 
• 1415680-14-6 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)benzyl benzoate 
• 1415680-16-8 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)benzyl-(4-acetoxy) cinnamate 
• 1415680-17-9 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)benzyl-(4-acetoxy-3-methoxy) cinnamate 
• 1590385-32-2 2-(2',3',4',6'-tetra-O-acetyl-βb-D-glucopyranosyloxy)benzyl(3-methoxy-4-acetoxy)benzoate 
• 1590385-40-2 2-(β-D-glucopyranosyloxy)benzyl (4-hydroxy)benzoate 
• 1590385-31-1 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)benzyl(4-acetoxy)benzoate 
• 5346-66-7 2-methylphenyl-(2,3,4,6-tetra-O-acetyl)-β-D-glucopyranoside 
• 7234-31-3 o-tolyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

First total chemical synthesis of natural acyl derivatives of some phenolglycosides of the family Salicaceae

The total synthesis of certain natural phenolglycosides of the family Salicaceae, namely: salireposide, populosides A, B, and C and not occurring in plants desoxysalireposide (2-(β-d-glucopyranosyloxy)-benzylbenzoate) and per-acetate of iso-salireposide (2-(β-d-glucopyranosyloxy)-5-benzoyloxy benzyl alcohol), starting from readily available phenols and glucose was accomplished. A simple method for the synthesis of phenolglycosides derivatives of 2-acyloxy salicyl and gentisyl alcohol was developed. The key step of these natural products' synthesis is a selective removal of acetyl groups in the presence of other acyl groups.