1222085-69-9Relevant academic research and scientific papers
Allylie substitution versus Suzuki cross-coupling: Capitalizing on chemoselectivity with bifunctional substrates
Hussain, Mahmud M.,Walsh, Patrick J.
, p. 1834 - 1837 (2010)
One catalyst, two reactions-a tale of chemoselectivity: Given the choice between an allylic acetate and a vinylboronate ester, palladium preferentially reacts with the allylic acetate to give the allylic substitution product. In the presence of an aryl bromide and base, Suzuki cross-coupling subsequently ensues to afford allylic amines (see scheme; pin = pinacol, THF = tetrahydrofuran). Chemical equation representation
