1222181-40-9Relevant academic research and scientific papers
Palladium-catalyzed cyclocarbonylation of arynes with methyl allyl carbonates: Selective synthesis of 1 H -inden-1-ones
Pi, Shao-Feng,Yang, Xu-Heng,Huang, Xiao-Cheng,Liang, Yun,Yang, Guan-Nan,Zhang, Xiao-Hong,Li, Jin-Heng
supporting information; experimental part, p. 3484 - 3487 (2010/08/05)
A selective protocol for the synthesis of 2-methylene-3-substituted-2,3- dihydro-1H-inden-1-ones and 2-benzylidene-2,3-dihydro-1H-inden-1-ones has been developed via palladium-catalyzed cyclocarbonylation reactions of arynes with allyl carbonates and carbon monooxide (CO). It is noteworthy that the selectivity of this new route is depended on both substrates and ligands.
