122244-57-9Relevant academic research and scientific papers
In Situ Generation of Silylzinc by Si?B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes
Nagashima, Yuki,Yukimori, Daiki,Wang, Chao,Uchiyama, Masanobu
, p. 8053 - 8057 (2018)
A new protocol has been designed for the in situ generation of unstable Si?Zn species through the reaction of dialkylzinc, phosphine, and silylborane (Si?B). Successive reactions with various terminal alkynes using this protocol enabled highly controllable regio-/stereo-/chemoselective silylzincation and silaboration on demand without the need for a transition-metal catalyst.
