122273-75-0Relevant academic research and scientific papers
Reductions by hydrides and hydroboration. The stereoselectivity of new access methods to 3-arylmethyl-4-chromanones (homoisoflavone derivatives)
Gomis,Kirkiacharian
, p. 1849 - 1858 (2007/10/02)
The reduction of 3-arylmethyl-4-chromanones by sodium borohydride, lithium tri-tert-butoxyaluminum hydride and hydroboration followed by oxydation of 3-benzyl-4-hydroxy-coumarines lead to mixtures of Cis and Trans diastereoisomers of 3-arylmethyl-4-chroma
Reduction par les hydrures : synthese et stereochimie des benzyl-3 chromannols-4
Gomis, M.,Kirkiacharian, B.S.,Likforman, J.,Mahuteau, J.
, p. 585 - 590 (2007/10/02)
Reduction of 3-arylidene 4-chromannones with lithium aluminium hydride leads in straightforward fashion to two 3-arylmethyl 4-chromannols diastereoisomers, for each derivative.Stereochemistry of 3-benzyl 4-chromanols is resolved by 1H and 13C NMR.Major trans compounds were obtained.
