122293-06-5Relevant academic research and scientific papers
Enantio- and diastereoselective reductive aldol reactions with iridium-pybox catalysts
Zhao, Cun-Xiang,Duffey, Matthew O.,Taylor, Steven J.,Morken, James P.
, p. 1829 - 1831 (2001)
(formula presented) A catalytic amount of [(cod)IrCl]2 and indane-pybox converts diethylmethylsilane, methyl acrylate, and certain aldehydes to the derived reductive aldol adduct with good enantio- and diastereocontrol.
Stereo-Modulating Catalysis by Europium(III) Complexes in Aldol Reactions of Chiral α-Alkoxy Aldehydes with Ketene Silyl Acetals
Terada, Masahiro,Gu, Jin-Hua,Deka, Dibakar C.,Mikami, Koichi,Nakai, Takeshi
, p. 29 - 32 (2007/10/02)
The Eu(fod)3- or Eu(dppm)3-catalyzed aldol reactions of the four chiral α-alkoxy aldehydes having different protecting groups with (E)- or (Z)-ketene silyl acetals are shown to provide the high levels of diasterocontrol, the sense depending on the nature
