1223462-51-8

Basic information

• Product Name: [Ru(η⁶-cymene)([2,6-iPr₂-(C₆H₃)NH]^-PPh₂)Cl₂]
• Synonyms: [Ru(η⁶-cymene)([2,6-iPr₂-(C₆H₃)NH]^-PPh₂)Cl₂]
• CAS NO: 1223462-51-8
• Molecular Weight: 667.664
• Mol File: 1223462-51-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Ru(η⁶-cymene)([2,6-iPr₂-(C₆H₃)NH]^-PPh₂)Cl₂](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(η⁶-cymene)([2,6-iPr₂-(C₆H₃)NH]^-PPh₂)Cl₂](1223462-51-8)
• EPA Substance Registry System: [Ru(η⁶-cymene)([2,6-iPr₂-(C₆H₃)NH]^-PPh₂)Cl₂](1223462-51-8)

Safety Data

• Hazardous Substances Data: 1223462-51-8(Hazardous Substances Data)

Upstream product

• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 1223462-45-0 N-(2,6-diisopropyl)phenyl-1,1-diphenylphosphanamine 

Relevant articles and documents

Role of the Trichlorostannyl Ligand in Tin–Ruthenium Arene Complexes: Experimental and Computational Studies

A set of neutral and ionic ruthenium arene trichlorostannyl complexes are reported herein. The tin(II) compounds L1SnCl {1; L1 = [2-(CH2NEt2)-4,6-(tBu)2C6H2]–} and [L2SnCl][SnCl3] {2; L2 = 2,6-[(CH3)C=N(C6H3-2,6-iPr2)2]C5H3N} showed a rather different reactivity towards the ruthenium complex [(η6-cymene)RuCl]2(η-Cl)2. As a consequence, the neutral complex [Ru(η6-cymene)(L1SnCl)Cl2] (4) and the ionic compound [L2SnCl][Ru(η6-cymene)(SnCl3)2Cl] (8) were isolated. The insertion reaction of 4 with SnCl2 provided the neutral trimetallic ruthenium complex [Ru(η6-cymene)(L1SnCl)(SnCl3)Cl] (6). Analogous ruthenium complexes [Ru(η6-cymene)(L3PPh2)Cl2] (5) and [Ru(η6-cymene)(L3PPh2)(SnCl3)Cl] (7) containing the phosphane ligand L3PPh2 {3; L3 = [2,6-iPr2-(C6H3)NH]–} were also prepared to evaluate the donor–acceptor strength of the tin(II)- and phosphorus-containing ligands. The structural characterization and DFT calculations of the above-mentioned complexes suggest a strong influence of the [SnCl3]– moiety on the Ru–E interaction (E = Sn, P). The influence of the trichlorostannyl ligand on the Ru–E interaction in the complexes 4–7 was further evaluated by means of a distortion/interaction analysis.