122347-07-3Relevant academic research and scientific papers
Synthetic Photochemistry. Part 44. Total Synthesis of Ceroplastol II and Albolic Acid, 5-8-5-Membered Tricyclic Sesterterpenoid Insect Wax Constituents, via Stereocontrolled Silyloxy-Cope Rearrangement with a Normally Disfavoured Transition State
Kato, Nobuo,Takeshita, Hitoshi,Kataoka, Hideo,Ohbuchi, Shoji,Tanaka, Shinya
, p. 165 - 174 (2007/10/02)
To a 1,5-diene, prepared by CrCl2-mediated condensation of two iridoid synthons, was appended a lactol moiety, which was subjected to a stereocontrolled silyloxy-Cope rearrangement to give, via a normally disfavoured boat transition geometry, a thermolysa
