122396-68-3Relevant academic research and scientific papers
Radical induced allylations of functionalized α-haloalkylphenyl sulfones
Giardina, Alessandra,Giovannini, Riccardo,Petrini, Marino
, p. 1995 - 1998 (2007/10/03)
α-Haloalkylphenyl sulfones are efficiently allylated using allyltributyltin in benzene at reflux in the presence of AIBN. Several functional groups (e.g. eater, keto, amino, nitro etc.) are tolerated by these conditions that ultimately allow the chemoselective allylation of phenylsulfones at α position.
Microbial Asymmetric Oxidation of 2-Alkoxyethylsulfides and a Facile Synthesis of Chiral Vinyl Sulfoxide
Ohta, Hiromichi,Matsumoto, Shinsuke,Okamoto, Yasushi,Sugai, Takeshi
, p. 625 - 628 (2007/10/02)
2-Alkoxyethyl phenyl sulfides were oxidized by incubation with Rhodococcus equi IFO 3730 to afford chiral sulfoxides of high enantio excess.Phenyl vinyl sulfoxide and 2-hydroxyethyl phenyl sulfoxide were obtained from microbial oxidation products without any loss their optical purities.
