122410-12-2Relevant academic research and scientific papers
Does the Wittig-Still rearrangement proceed via a metal free carbanion?
Kruse,Bruckner
, p. 4425 - 4428 (2007/10/02)
The steric course of [2,3] rearrangements of allyloxy methanides is almost not affected by the counterion (M = Li, Na, K, Rb, Cs) as demonstrated by the nearly metal independent E,Z and anti,syn selectivities of rearrangements 4→6 and 7→8, respectively.
Reductive Lithiation of Sulfides and Sulfones - A Novel Entry into Wittig Rearrangements
Kruse, Birgit,Brueckner, Reinhard
, p. 2023 - 2026 (2007/10/02)
The reductive cleavages of allyl ethers (8, 11) and an allyl ether (14) with lithium naphthalenide in THF furnish homoallylic alcohols (9, 12).The steric course of these transformations (E/Z selectivity in the
