122437-52-9Relevant academic research and scientific papers
INSECT ANTIFEEDANTS FROM AZADIRACHTA INDICA (PART 5): CHEMICAL MODIFICATION AND STRUCTURE-ACTIVITY RELATIONSHIPS OF AZADIRACHTIN AND SOME RELATED LIMONOIDS
Ley, Steven V.,Anderson, James C.,Blaney, Wally M.,Jones, Philip S.,Lidert, Zev,Morgan, David E.
, p. 5175 - 5192 (2007/10/02)
Chemical modification of the potent insect antifeedant and growth-disruption agent azadirachtin (1) and the related limonoids 3-tigloyl azadirachtol (6) and salannin (27) have permitted an exploration of the biological activity of these compounds.General
CHEMISTRY OF INSECT ANTIFEEDANTS FROM AZADIRACHTA INDICA (Part 3) REACTIONS ON THE C-22,23 ENOL ETHER DOUBLE BOND OF AZADIRACHTIN AND CONVERSION TO 22,23-DIHYDRO-23-&β-METHOXYAZADIRACHTIN.
Ley, Steven V.,Anderson, James C.,Blaney, Wally M.,Lidert, Zev,Morgan, E. David,et al.
, p. 5433 - 5436 (2007/10/02)
Azadirachtin (1) can be converted to the natural product 22,23-dihydro-23β-methoxyazadirachtin (2) via selective bromomethoxylation of the C-22,23 enol ether double bond and tri-n-butyltin hydride reduction; the corresponding acetic acid adduct on pyrolysis affords (1) in high yield.The antifeedant effects of the addition compounds were assessed.
