1224742-10-2

Basic information

• Product Name: [Cp(*)Fe(SEt)(η2-SC(SEt)NPh)]
• CAS NO: 1224742-10-2
• Molecular Weight: 448.521
• Mol File: 1224742-10-2.mol

Chemical Properties

• CAS DataBase Reference: [Cp(*)Fe(SEt)(η2-SC(SEt)NPh)](CAS DataBase Reference)
• NIST Chemistry Reference: [Cp(*)Fe(SEt)(η2-SC(SEt)NPh)](1224742-10-2)
• EPA Substance Registry System: [Cp(*)Fe(SEt)(η2-SC(SEt)NPh)](1224742-10-2)

Safety Data

• Hazardous Substances Data: 1224742-10-2(Hazardous Substances Data)

Upstream product

• 103-72-0 phenyl isothiocyanate 

Relevant articles and documents

Insertion reactions of CS2, COS, and PhNCS at thiolate-bridged diiron centers

Treatment of [Cp*Fe(μ2-SR)3FeCp*] (1a, R = Et; 1b, R = Me) with CS2 obtains the insertion products [Cp*Fe(μ2-SR)2(μ-η2-S 2CSR)FeCp*] (2a, R = Et; 2b, R = Me) with the retained Fe 2S2 subunit in excellent yield. 2a and 2b represent the first examples for the CS2 activation and incorporation at the diiron-SR bond. [Cp*Fe(μ2-SEt)2(μ- η2-S2)FeCp*] (3) is prepared from COS and 1a through the decarbonylation and sulfur coupling reaction of COS resulting in the formation of S22- ligand. Addition of PhNCS into 1a affords a mononuclear complex [Cp*Fe(SEt)(η2-SC(SEt)NPh)] (4). 1a is found to be unreactive towards CO2. The spectral characterization, X-ray diffraction analysis, and electrochemistry of the insertion products have also been described.