1224840-08-7Relevant articles and documents
Synthesis of chiral 2-phospha[3]ferrocenophanes and their behaviour as organocatalysts in [3+2]Cyclization reactions
Voituriez, Arnaud,Panossian, Armen,Fleury-Bregeot, Nicolas,Retailleau, Pascal,Marinetti, Angela
, p. 1968 - 1976 (2009)
Planar chiral 2-phospha[3]ferrocenophanes have been prepared via a stereoselective three-step synthesis. The key step is the lithiation of the l,1′-disubstituted ferrocene 11 bearing (S)-2-(methoxymethyl)pyrrolidines as the chiral ortho-directing groups.