1224875-73-3Relevant academic research and scientific papers
Nitrosonium ion catalysis: aerobic, metal-free cross-dehydrogenative carbon-heteroatom bond formation
Bering, Luis,D'Ottavio, Laura,Sirvinskaite, Giedre,Antonchick, Andrey P.
supporting information, p. 13022 - 13025 (2018/11/23)
Catalytic cross-dehydrogenative coupling of heteroarenes with thiophenols and phenothiazines has been developed under mild and environmentally benign reaction conditions. For the first time, NOx+ was applied for catalytic C-S and C-N bond formation. A comprehensive scope for the C-H/S-H and C-H/N-H cross-dehydrogenative coupling was demonstrated with >60 examples. The sustainable cross-coupling conditions utilize ambient oxygen as the terminal oxidant, while water is the sole by-product.
The use of anhydrous CeCl3 as a catalyst for the synthesis of 3-sulfenyl indoles
Silveira, Claudio C.,Mendes, Samuel R.,Wolf, Lucas,Martins, Guilherme M.
experimental part, p. 2014 - 2016 (2010/06/14)
Anhydrous CeCl3 was successfully used as a catalyst for the synthesis of several 3-sulfenyl indoles in good to excellent yields through the reaction of indole with N-(alkylthio) and N-(arylthio)phthalimides in DMF.
