122489-62-7

Basic information

• Product Name: thallium 2,4,6-tris(trifluoromethyl)phenoxide
• CAS NO: 122489-62-7
• Molecular Weight: 1002.97
• Mol File: 122489-62-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: thallium 2,4,6-tris(trifluoromethyl)phenoxide(CAS DataBase Reference)
• NIST Chemistry Reference: thallium 2,4,6-tris(trifluoromethyl)phenoxide(122489-62-7)
• EPA Substance Registry System: thallium 2,4,6-tris(trifluoromethyl)phenoxide(122489-62-7)

Safety Data

• Hazardous Substances Data: 122489-62-7(Hazardous Substances Data)

Upstream product

• 20398-06-5 thallium (I) ethoxide 
• 122489-60-5 2,4,6-tris(trifluoromethyl)phenol 

Relevant articles and documents

Preparation and crystal structure of thallium 2,4,6-tris(trifluoromethyl)phenoxide, a compound of thallium(I) with coordination number 2 at the thallium atom

The reaction of C6H2(CF3)3Li and (Me3Si)2O2 results in the formation of C6H2(CF3)3OSiMe3 (5), which is converted by hydrogen chloride to the phenol C6H2(CF3)3OH (4). 4 reacts with TlOC2H5 to give the title compound [C6H2(CF3)3OTl]2 (6). Mass spectroscopic and X-ray structural analyses confirm the dimeric structure with Tl(I) of coordination number 2. [C6H2(CF3)3OTl]2 crystallizes in the space group P21/c with a = 1257.5 (7) pm, b = 946.1 (7) pm, c = 1060.9 (5) pm, and β = 101.41 (4)°.