1224892-92-5

Upstream product

• 1224892-91-4 (5S,6S,7S,8S,E)-9-(tert-butyldiphenylsilyloxy)-5-hydroxy-7-(4-methoxybenzyloxy)-6,8-dimethylnon-2-enyl acetate 

Downstream Products

• 1224892-93-6 (2S,4S,5S)-5-methyl-2-phenyl-4-((S)-1-((2R,4S,6R)-2-phenyl-6-vinyl-1,3-dioxan-4-yl)ethyl)-1,3-dioxane 
• 1224892-97-0 (2S,3S,4S)-1-hydroxy-2-methyl-4-((2S,4S,6R)-2-phenyl-6-vinyl-1,3-dioxan-4-yl)pentan-3-yl 4-methoxybenzoate 
• 1224892-96-9 C₄₂H₅₀O₆Si 

Relevant academic research and scientific papers

Regio- and stereocontrol in rhenium-catalyzed transposition of allylic alcohols

A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.