122490-45-3

Upstream product

• 122490-44-2 (4aR,6R,8aS)-4,4a,6,8a-Tetrahydro-2,2-dimethylpyrano<3,2-d>-m-dioxin-6-propanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 82740-87-2 (2R,3S,6R)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl acetate 
• 122490-43-1 (4aR,6R,8aS)-6-Allyl-4,4a,6,8a-tetrahydro-2,2-dimethylpyrano<3,2-d>-m-dioxin 
• 95791-07-4 (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 

Downstream Products

• 122490-76-0 tert-Butyl-[3-((4aR,6R,8aS)-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propoxy]-diphenyl-silane 
• 122490-48-6 (4aR,8aS)-4,4a,8,8a-Tetrahydro-6-[3-(tert-butyldiphenylsiloxy)propyl]-2,2-dimethylpyrano-[3,2-d]-m-dioxin 
• 180478-12-0 Toluene-4-sulfonic acid (2R,3S,6R)-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-tetrahydro-pyran-2-ylmethyl ester 
• 180478-16-4 tert-Butyl-[3-((2R,5S,6S)-5-methoxy-1,7-dioxa-spiro[5.5]undec-2-yl)-propoxy]-diphenyl-silane 
• 180478-15-3 4-{(2R,3S,6R)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-3-methoxy-tetrahydro-pyran-2-yl}-butan-1-ol 
• 180478-14-2 [3-((2R,5S,6R)-6-But-3-enyl-5-methoxy-tetrahydro-pyran-2-yl)-propoxy]-tert-butyl-diphenyl-silane 
• 180478-13-1 (2R,3S,6R)-2-But-3-enyl-6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-tetrahydro-pyran-3-ol 
• 180478-11-9 (2R,3S,6R)-6-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-2-hydroxymethyl-tetrahydro-pyran-3-ol 

Relevant academic research and scientific papers

Synthesis of the ABC Ring System of Brevetoxin B

A synthesis of the ABC ring framework of brevetoxin B is described.The optically active intermediate 2 representing the ABC ring system and equipped with appropriate functionality for further elaboration is constructed from glucal triacetate.The reported