1224969-70-3

Basic information

• Product Name: dicobalttetracarbonyl(μ-phenylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)
• Synonyms: dicobalttetracarbonyl(μ-phenylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)
• CAS NO: 1224969-70-3
• Molecular Weight: 739.56
• Mol File: 1224969-70-3.mol

Chemical Properties

• CAS DataBase Reference: dicobalttetracarbonyl(μ-phenylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)(CAS DataBase Reference)
• NIST Chemistry Reference: dicobalttetracarbonyl(μ-phenylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)(1224969-70-3)
• EPA Substance Registry System: dicobalttetracarbonyl(μ-phenylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)(1224969-70-3)

Safety Data

• Hazardous Substances Data: 1224969-70-3(Hazardous Substances Data)

Upstream product

• 12154-91-5 (phenylacetylene)hexacarbonyldicobalt 
• 1224969-63-4 N-benzyl-N-diphenylphosphanyl-3,5-bis(trifluoromethyl)phenylsulfinamide borane complex 

Downstream Products

• 41577-61-1 (-)-(3aR,4S,7R,7aR)-2-phenyl-3a,4,7,7a-tetrahydro-1H-4,7-methanoinden-1-one 

Relevant articles and documents

PNSO ligands as a tool to study metal bonding of electron-deficient sulfinyl groups

A family of N-phosphanylsulfinamide (PNSO) ligands with electron-deficient sulfinyl groups was synthesized. Reaction with Co2-alkyne complexes yields P,S-bridged complexes. These complexes were used to study the metal bonding of different sulfinyl groups. IR spectroscopy, X-ray analysis, and Pauson-Khand reactivity studies indicated that electron-deficient sulfinyl groups provide enhanced S metal bonding. The mean CO stretching frequencies (Δv) for these complexes closely correlates with the χi parameter computed by Tolman for phosphane ligands. Among the studied sulfinyl groups, the trifluoromethyl PNSO ligand afforded the strongest sulfur-metal bond. Wiley-VCH Verlag GmbH & Co. KGaA.