1224974-36-0Relevant academic research and scientific papers
A novel tetra(tetrathiafulvalene-thiacrown ether)-substituted porphyrazine: Synthesis, electro-chemical, and control aggregation in solution by complexation of transition-metal ions
Hou, Ruibin,Jiang, Cuiping,Yin, Bingzhu
, p. 717 - 725 (2010)
Synthesis of a novel magnesium porphyrazine 6, peripherally substituted with S4 crown ether-TTF macrocycles was described. Molecular structure has been fully characterized by 1H-NMR, IR, MS, and elemental analysis. Crystal structure of the precursor was determined by X-ray crystallography. Their solution electrochemical data showed two reductive and three oxidative processes within a -1.3 V to -1.5 V potential window. UV/Vis spectroscopy and electron paramagnetic resonance (EPR) measurements revealed the formation of a charge-transfer complex between porphyrazine 6 with F4TCNQ. UV/vis spectroscopy showed that addition of the transition-metal ions led to dimerization of the porphyrazine complexes.
