1224975-67-0Relevant academic research and scientific papers
Aliphatic polyketones via cross-metathesis polymerization: Synthesis and post-polymerization modification
Zeng, Fu-Rong,Xu, Jing,Xiong, Qi,Qin, Kai-Xuan,Xu, Wei-Jun,Wang, Yue-Xin,Liu, Zan-Jiao,Li, Zi-Long,Li, Zi-Chen
, (2019)
Polyolefins attract considerable attention due to their vast consumption and wide application. In this study, cross-metathesis polymerization (CMP) is demonstrated to be an efficient and feasible method for the synthesis of aliphatic polyketones. The synt
Rongalite and base-promoted cleavage of disulfides and subsequent Michael addition to α,β-unsaturated ketones/esters: an odorless synthesis of β-sulfido carbonyl compounds
Guo, Wenxue,Lv, Guangshu,Chen, Jiuxi,Gao, Wenxia,Ding, Jinchang,Wu, Huayue
supporting information; experimental part, p. 2297 - 2300 (2010/06/16)
A highly practical method to access β-sulfido carbonyl compounds was developed, which could be conducted without any expensive reagent, special apparatus/technique, and no requirement of metal catalysts. β-Sulfido carbonyl compounds were formed at room temperature, in short time and with high chemoselectivity in good to excellent yields. A plausible mechanism for the role of Rongalite, as a promoter for the cleavage of disulfides generating thiolate anions that then undergo facile thia-Michael addition to α,β-unsaturated ketones and esters is proposed.
