122566-01-2Relevant academic research and scientific papers
Asymmetric induction in Diels-Alder reactions of α-alkoxyorthoquinodimethanes
Charlton, James L.,Plourde, Guy L.,Penner, Glenn H.
, p. 1010 - 1014 (2007/10/02)
It has been shown that dienophiles cycloadd selectively to one face of o-quinodimethanes (o-QDMs) bearing chiral α-alkoxy groups.The face selectivity (diastereoselectivity) increases for the series of chiral groups -OCH(Ph)CH3, -OCH(Ph)CH3(CH3)2, and -OCH
Diastereoselectivity and asymmetric induction in the Diels-Alder reaction of o-quinodimethanes
Charlton, James L.
, p. 720 - 725 (2007/10/02)
The extent of asymmetric induction in the bimolecular Diels-Alder reactions of chiral o-quinodimethanes with dimethyl fumarate, methyl acrylate, and maleic anhydride has been studied. o-Quinodimethanes with chiral α-alkoxy groups were prepared from 1-alko
