122576-23-2Relevant academic research and scientific papers
The coordination chenistry of iminooxosulphuranes. III. Synthesis of the ruthenium complexes (L=CO, CNtBu, CNC6H3Me2-2,6; R=C6H4Me-2, C6H4Me-4)
Herberhold, Max,Hill, Anthony F.
, p. 111 - 118 (1989)
The tris(phosphine) complexes (L=CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes, RN=S=O, (R=C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide .Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur.Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.
