122601-46-1Relevant academic research and scientific papers
High π-route reactivity in the tropene system. Absence of a nitrogen acceleration effect
Murr, Brown L.,Parkhill, Billy J.,Nickon, Alex
, p. 4845 - 4862 (2007/10/02)
Solvolyses of a suitably constructed tropene tosylate and its unsaturated carbocyclic analog show that the amino function, despite its suitable spatial location, does not enhance the π-route assistance but reduces it slightly.
Absence of heteroatom kinetic effects in π-routes to carbocations
Nickon, Alex,Jones, Stella S.,Parkhill, Billy J.
, p. 187 - 194 (2007/10/02)
In solvolyses of prototypical tricyclic and bicyclic heterocycles, suitably positioned oxygen, nitrogen, or sulfur ring-atoms have little net kinetic influence on π routes to carbocations.
